Pre‐drill Groundwater Geochemistry in the Karoo Basin,South Africa          下载免费PDF全文

Jennifer S. Harkness  Kelley Swana  William K. Eymold  Jodie Miller  Ricky Murray  Siep Talma  Colin J. Whyte  Myles T. Moore  Erica L. Maletic  Avner Vengosh  Thomas H. Darrah 《Ground water》2018,56(2):187-203

Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin.  相似文献   

It’s Time To Learn About Learning: Where Should the Environmental and Natural Resource Governance Field Go Next?     

Andrea K. Gerlak  Tanya Heikkila  Sharon L. Smolinski  Derek Armitage  Dave Huitema  Brendan Moore 《社会与自然资源》2019,32(9):1056-1064

This Commentary reflects on the state of the scholarship on learning for environmental and natural resource policy and governance. How have we been learning about learning? We highlight theoretical and empirical advancements related to learning, as well as areas of divergence between learning theories and frameworks, and underdeveloped knowledge around processes and outcomes. To address these limitations and improve progress in both theory and practice, we offer recommendations for learning scholarship by focusing on how to collectively engage in ‘learning about learning’.  相似文献   

The Regional Ocean Modeling System (ROMS) 4-dimensional variational data assimilation systems: Part II - Performance and application to the California Current System     

Andrew M. Moore  Hernan G. ArangoGregoire Broquet  Chris EdwardsMilena Veneziani  Brian PowellDave Foley  James D. DoyleDan Costa  Patrick Robinson 《Progress in Oceanography》2011,91(1):50-73

The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems.  相似文献   

A geomorphological mapping approach for the assessment of seabed geohazards and risk     

Gayle Hough  Jennifer Green  Paul Fish  Andy Mills  Roger Moore 《Marine Geophysical Researches》2011,32(1-2):151-162

Exploration and development of offshore hydrocarbon resources has advanced into remote deepwater regions over the last decade and poses significant technical challenges for the design and installation of wells and facilities at extreme water depths. Seafloor and shallow subsurface processes and conditions in these areas are complex and generally poorly understood, and the geohazards to development are larger scale and fundamentally different to those encountered onshore; consequently the geohazard risk to deepwater development projects is potentially significant and requires careful evaluation and mitigation during the front-end planning and engineering design stages of projects. There are no established industry standards or methods for the assessment of geohazards and engineering-quality geophysical data at the scale of development. The paper describes an integrated and systematic map-based approach for the assessment and mitigation of seabed geohazards and risk to proposed deepwater development. The approach employs a multi-disciplinary team working with engineering-quality field calibrated data to accurately map and assess seafloor ground conditions and ensure that development proposals are not exposed to intolerable geohazard risk. The approach taken is very similar to the practice of establishing geological models for land-based engineering projects, in which the complete geological history of the site is used to characterise and predict the performance of the ground. Such an approach is routine for major projects on land but so far does not seem to be common practice in the offshore industry. The paper illustrates the seafloor geomophological mapping approach developed. The products are being used to optimise development layouts to avoid geohazards where possible and to support site-specific engineering design of facilities based on a detailed understanding of the potential geohazard loadings and associated risk.  相似文献   

Upwelling in the Alaskan Beaufort Sea: Atmospheric forcing and local versus non-local response     

Robert S. Pickart  Michael A. Spall  G.W.K. Moore  Thomas J. Weingartner  Rebecca A. Woodgate  Knut Aagaard  Koji Shimada 《Progress in Oceanography》2011,88(1-4):78-100

The spin up and relaxation of an autumn upwelling event on the Beaufort slope is investigated using a combination of oceanic and atmospheric data and numerical models. The event occurred in November 2002 and was driven by an Aleutian low storm. The wind field was strongly influenced by the pack-ice distribution, resulting in enhanced winds over the open water of the Chukchi Sea. Flow distortion due to the Brooks mountain range was also evident. Mooring observations east of Barrow Canyon show that the Beaufort shelfbreak jet reversed to the west under strong easterly winds, followed by upwelling of Atlantic Water onto the shelf. After the winds subsided a deep eastward jet of Atlantic Water developed, centered at 250 m depth. An idealized numerical model reproduces these results and suggests that the oceanic response to the local winds is modulated by a propagating signal from the western edge of the storm. The disparity in wave speeds between the sea surface height signal—traveling at the fast barotropic shelf wave speed—versus the interior density signal—traveling at the slow baroclinic wave speed—leads to the deep eastward jet. The broad-scale response to the storm over the Chukchi Sea is investigated using a regional numerical model. The strong gradient in windspeed at the ice edge results in convergence of the offshore Ekman transport, leading to the establishment of an anti-cyclonic gyre in the northern Chukchi Sea. Accordingly, the Chukchi shelfbreak jet accelerates to the east into the wind during the storm, and no upwelling occurs west of Barrow Canyon. Hence the storm response is fundamentally different on the Beaufort slope (upwelling) versus the Chukchi slope (no upwelling). The regional numerical model results are supported by additional mooring data in the Chukchi Sea.  相似文献   

Corrections to ocean surface forcing in the California Current System using 4D variational data assimilation     

G. Broquet  A.M. Moore  H.G. Arango  C.A. Edwards 《Ocean Modelling》2011,36(1-2):116-132

The option for surface forcing correction, recently developed in the 4D-variational (4DVAR) data assimilation systems of the Regional Ocean Model System (ROMS), is presented. Assimilation of remotely-sensed (satellite sea surface height anomaly and sea surface temperature) and in situ (from mechanical and expendable bathythermographs, Argo floats and CTD profiles) oceanic observations has been applied in a realistic, high resolution configuration of the California Current System (CCS) to sequentially correct model initial conditions and surface forcing, using the Incremental Strong constraint version of ROMS-4DVAR (ROMS-IS4DVAR). Results from both twin and real data experiments are presented where it is demonstrated that ROMS-IS4DVAR always reduces the difference between the model and the observations that are assimilated. However, without corrections to the surface forcing, the assimilation of surface data can degrade the temperature structure at depth. When using surface forcing adjustment in ROMS-IS4DVAR the system does not degrade the temperature structure at depth, because differences between the model and surface observations can be reduced through corrections to surface forcing rather than to temperature at depth. However, corrections to surface forcing can generate abnormal spatial and temporal variability in the structure of the wind stress or surface heat flux fields if not properly constrained. This behavior can be partially controlled via the choice of decorrelation length scales that are assumed for the forcing errors. Abnormal forcing corrections may also arise due to the effects of model error which are not accounted for in IS4DVAR. In particular, data assimilation tends to weaken the alongshore wind stress in an attempt to reduce the rate of coastal upwelling, which seems to be too strong due to other sources of error. However, corrections to wind stress and surface heat flux improve systematically the ocean state analyses. Trends in the correction of surface heat fluxes indicate that, given the ocean model used and its potential limitations, the heat flux data from the Coupled Ocean–Atmosphere Mesoscale Prediction System (COAMPS) used to impose surface conditions in the model are generally too low except in spring-summer, in the upwelling region, where they are too high. Comparisons with independent data provide confidence in the resulting forecast ocean circulation on timescales ～14 days, with less than 1.5 °C, 0.3 psu, and 9 cm RMS error in temperature, salinity and sea surface height anomaly, respectively, compared to observations.  相似文献   

Contrasting isotopic signatures between anthropogenic and geogenic Zn and evidence for post-depositional fractionation processes in smelter-impacted soils from Northern France   总被引：2，自引：0，他引：2  

Farid Juillot  Delphine Jouvin  Philipe Telouk  Philippe Ildefonse  Steve Sutton  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308

Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ⁶⁶Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ⁶⁶Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ⁶⁶Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe₂O₄)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ⁶⁶Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ⁶⁶Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ⁶⁶Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments.  相似文献   

Sedimentary Deposits from the 17 July 2006 Western Java Tsunami,Indonesia: Use of Grain Size Analyses to Assess Tsunami Flow Depth,Speed, and Traction Carpet Characteristics     

Andrew Moore  James Goff  Brian G. McAdoo  Hermann M. Fritz  Aditya Gusman  Nikos Kalligeris  Kenia Kalsum  Arif Susanto  Debora Suteja  Costas E. Synolakis 《Pure and Applied Geophysics》2011,168(11):1951-1961

The 2006 western Java tsunami deposited a discontinuous sheet of sand up to 20 cm thick, flooded coastal southern Java to a depth of at least 8 m and inundated up to 1 km inland. In most places the primarily heavy mineral sand sheet is normally graded, and in some it contains complex internal stratigraphy. Structures within the sand sheet probably record the passage of up to two individual waves, a point noted in eyewitness accounts. We studied the 2006 tsunami deposits in detail along a flow parallel transect about 750 m long, 15 km east of Cilacap. The tsunami deposit first becomes discernable from the underlying sediment 70 m from the shoreline. From 75 to 300 m inland the deposit has been laid down in rice paddies, and maintains a thickness of 10–20 cm. Landward of 300 m the deposit thins dramatically, reaching 1 mm by 450 m inland. From 450 m to the edge of deposition (around 700 m inland) the deposit remains <1 mm thick. Deposition generally attended inundation—along the transect, the tsunami deposited sand to within about 40 m of the inundation limit. The thicker part of the deposit contains primarily sand indistinguishable from that found on the beach 3 weeks after the event, but after about 450 m (and roughly coinciding with the decrease in thickness) the tsunami sediment shifts to become more like the underlying paddy soil than the beach sand. Grain sizes within the deposit tend to fine upward and landward, although overall upward fining takes place in two discrete pulses, with an initial section of inverse grading followed by a section of normal grading. The two inversely graded sections are also density graded, with denser grains at the base, and less dense grains at the top. The two normally graded sections show no trends in density. The inversely graded sections show high density sediment to the base and become less dense upward and represents traction carpet flows at the base of the tsunami. These are suggestive of high shear rates in the flow. Because of the grain sorting in the traction carpet, the landward-fining trends usually seen in tsunami deposits are masked, although lateral changes of mean sediment grain size along the transect do show overall landward fining, with more variation as the deposit tapers off. The deposit is also thicker in the more seaward portions than would be produced by tsunamis lacking traction carpets.  相似文献   

A GIS-based method for defining snow zones: application to the western United States     

Cara Moore  Brandon Stone  Eric Richer 《国际地球制图》2015,30(1):62-81

This study maps the geographic extent of intermittent and seasonal snow cover in the western United States using thresholds of 2000–2010 average snow persistence derived from moderate resolution imaging spectroradiometer snow cover area data from 1 January to 3 July. Results show seasonal snow covers 13% of the region, and intermittent snow covers 25%. The lower elevation boundaries of intermittent and seasonal snow zones increase from north-west to south-east. Intermittent snow is primarily found where average winter land surface temperatures are above freezing, whereas seasonal snow is primarily where winter temperatures are below freezing. However, temperatures at the boundary between intermittent and seasonal snow exhibit high regional variability, with average winter seasonal snow zone temperatures above freezing in west coast mountain ranges. Snow cover extent at peak accumulation is most variable at the upper elevations of the intermittent snow zone, highlighting the sensitivity of this snow zone boundary to climate conditions.  相似文献   

Landscape controls on long‐term runoff in subhumid heterogeneous Boreal Plains catchments          下载免费PDF全文

Kevin J. Devito  Kelly J. Hokanson  Paul Adrian Moore  Nicholas Kettridge  Axel E. Anderson  Laura Chasmer  Chris Hopkinson  Maxwell C. Lukenbach  Carl A. Mendoza  Julienne Morissette  Daniel L. Peters  Richard Michael Petrone  Uldis Silins  Brian Smerdon  James Michael Waddington 《水文研究》2017,31(15):2737-2751

We compared median runoff (R) and precipitation (P) relationships over 25 years from 20 mesoscale (50 to 5,000 km²) catchments on the Boreal Plains, Alberta, Canada, to understand controls on water sink and source dynamics in water‐limited, low‐relief northern environments. Long‐term catchment R and runoff efficiency (RP^?1) were low and varied spatially by over an order of magnitude (3 to 119 mm/year, 1 to 27%). Intercatchment differences were not associated with small variations in climate. The partitioning of P into evapotranspiration (ET) and R instead reflected the interplay between underlying glacial deposit texture, overlying soil‐vegetation land cover, and regional slope. Correlation and principal component analyses results show that peatland‐swamp wetlands were the major source areas of water. The lowest estimates of median annual catchment ET (321 to 395 mm) and greatest R (60 to 119 mm, 13 to 27% of P) were observed in low‐relief, peatland‐swamp dominated catchments, within both fine‐textured clay‐plain and coarse‐textured glacial deposits. In contrast, open‐water wetlands and deciduous‐mixedwood forest land covers acted as water sinks, and less catchment R was observed with increases in proportional coverage of these land covers. In catchments dominated by hummocky moraines, long‐term runoff was restricted to 10 mm/year, or 2% of P. This reflects the poor surface‐drainage networks and slightly greater regional slope of the fine‐textured glacial deposit, coupled with the large soil‐water and depression storage and higher actual ET of associated shallow open‐water marsh wetland and deciduous‐forest land covers. This intercatchment study enhances current conceptual frameworks for predicting water yield in the Boreal Plains based on the sink and source functions of glacial landforms and soil‐vegetation land covers. It offers the capability within this hydro‐geoclimatic region to design reclaimed catchments with desired hydrological functionality and associated tolerances to climate or land‐use changes and inform land management decisions based on effective catchment‐scale conceptual understanding.  相似文献